Alcohols are converted to alkyl halides by S N 1 and S N 2 reactions with halogen acids. A more efficient method of preparing alkyl halides from alcohols involves reactions with thionyl chloride (SOCl 2). The overall type of reaction is the same as that in the conversion of isopropyl alcohol to acetone. Tertiary alcohols (R 3 COH) are resistant to oxidation because the carbon atom that carries the OH group does not have a hydrogen atom attached but is instead bonded to other carbon atoms. The oxidation reactions we have described involve the formation of a carbon-to-oxygen double bond.

Primary alcohols favor S N 2 substitutions while S N 1 substitutions occur mainly with tertiary alcohols. Alcohol - Alcohol - Reactions of alcohols: Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Academia.edu is a platform for academics to share research papers. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.

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